Pi Jessie has a FAT32 boot partition and this allows Windows to 'see' the basic system configuration files. However the rest of Jessie (including the network setup files) are all on the *nix Ext4 partition, which is 'invisible' to Windows.
The only software I have found capable of accessing (read/write) the Ext4 partition is Paragon ExtFS for Windows. This is 'commercial' software but the 'Free trial' version does the job (when the trial 'times out' it limits the read/write speed to 5mbs, but still has all the functionality you need).
Windows 7 (or later) users can install the current version, Paragon ExtFS for Windows (the 5Mbs free trial limitation won't stop you making edits). If you can't get it from Paragon, you can download it from here Windows XP users need the older version. One source that won't try to 'hi-jack' your PC (with some 'Driver Installer' or other Adware Trojan) is this German download site. If that link fails to work, right click, and 'save link as' Paragon_ExtFS_for_Windows_2.1.440.exe here.After install, WinPatrol will pop-up twice = once for the 'update service' (reject, unless you want Paragon to update you to the non-XP version :-) ) and again for the 'driver' (allow).
Note, you will need to reboot your PC to get the 'service' to launch correctly, after which the SDHC Ext4 partition should appear in Windows Explorer (My Computer) as a new drive letter